Search for new resonant states in 10C and 11C and their impact on the cosmological lithium problem

The observed primordial 7Li abundance in metal-poor halo stars is found to be lower than its Big-Bang nucleosynthesis (BBN) calculated value by a factor of approximately three. Some recent works suggested the possibility that this discrepancy originates from missing resonant reactions which would destroy the 7Be, parent of 7Li. The most promising candidate resonances which were found include a possibly missed 1- or 2- narrow state around 15 MeV in the compound nucleus 10C formed by 7Be+3He and a state close to 7.8 MeV in the compound nucleus 11C formed by 7Be+4He. In this work, we studied the high excitation energy region of 10C and the low excitation energy region in 11C via the reactions 10B(3He,t)10C and 11B(3He,t)11C, respectively, at the incident energy of 35 MeV. Our results for 10C do not support 7Be+3He as a possible solution for the 7Li problem. Concerning 11C results, the data show no new resonances in the excitation energy region of interest and this excludes 7Be+4He reaction channel as an explanation for the 7Li deficit.Comment: Accepted for publication in Phys. Rev. C (Rapid Communication

Stationarity, soft ergodicity, and entropy in relativistic systems

Recent molecular dynamics simulations show that a dilute relativistic gas equilibrates to a Juettner velocity distribution if ensemble velocities are measured simultaneously in the observer frame. The analysis of relativistic Brownian motion processes, on the other hand, implies that stationary one-particle distributions can differ depending on the underlying time-parameterizations. Using molecular dynamics simulations, we demonstrate how this relativistic phenomenon can be understood within a deterministic model system. We show that, depending on the time-parameterization, one can distinguish different types of soft ergodicity on the level of the one-particle distributions. Our analysis further reveals a close connection between time parameters and entropy in special relativity. A combination of different time-parameterizations can potentially be useful in simulations that combine molecular dynamics algorithms with randomized particle creation, annihilation, or decay processes.Comment: 4 page

Generating potentials via difference equations

The condition for pressure isotropy, for spherically symmetric gravitational fields with charged and uncharged matter, is reduced to a recurrence equation with variable, rational coefficients. This difference equation is solved in general using mathematical induction leading to an exact solution to the Einstein field equations which extends the isotropic model of John and Maharaj. The metric functions, energy density and pressure are well behaved which suggests that this model could be used to describe a relativistic sphere. The model admits a barotropic equation of state which approximates a polytrope close to the stellar centre.Comment: 11 pages, To appear in Math. Meth. Appl. Sc

Missing linkers : an alternative pathway to UiO-66 electronic structure engineering

UiO-66 is a promising metal-organic framework for photocatalytic applications. However, the ligand-to-metal charge transfer of an excited electron is inefficient in the pristine material. Herein, we assess the influence of missing linker defects on the electronic structure of UiO-66 and discuss their ability to improve ligand-to-metal charge transfer. Using a new defect classification system, which is transparent and easily extendable, we identify the most promising photocatalysts by considering both relative stability and electronic structure. We find that the properties of UiO-66 defect structures largely depend on the coordination of the constituent nodes and that the nodes with the strongest local distortions alter the electronic structure most. Defects hence provide an alternative pathway to tune UiO-66 for photocatalytic purposes, besides linker modification and node metal substitution. In addition, the decomposition of MOF properties into node- and linker-based behavior is more generally valid, so we propose orthogonal electronic structure tuning as a paradigm in MOF design

Gas Metallicity in the Narrow-Line Regions of High-Redshift Active Galactic Nuclei

We analyze optical (UV rest-frame) spectra of X-ray selected narrow-line QSOs at redshift 1.5 < z < 3.7 found in the Chandra Deep Field South and of narrow-line radio galaxies at redshift 1.2 < z < 3.8 to investigate the gas metallicity of the narrow-line regions and their evolution in this redshift range. Such spectra are also compared with UV spectra of local Seyfert 2 galaxies. The observational data are inconsistent with the predictions of shock models, suggesting that the narrow-line regions are mainly photoionized. The photoionization models with dust grains predict line flux ratios which are also in disagreement with most of the observed values, suggesting that the high-ionization part of the narrow-line regions (which is sampled by the available spectra) is dust-free. The photoionization dust-free models provide two possible scenarios which are consistent with the observed data: low-density gas clouds (n < 10^3 cm^-3) with a sub-solar metallicity (0.2 < Z/Z_sun < 1.0), or high-density gas clouds (n ~ 10^5 cm^-3) with a wide range of gas metallicity (0.2 < Z/Z_sun < 5.0). Regardless of the specific interpretation, the observational data do not show any evidence for a significant evolution of the gas metallicity in the narrow-line regions within the redshift range 1.2 < z < 3.8. Instead, we find a trend for more luminous active galactic nuclei to have more metal-rich gas clouds (luminosity-metallicity relation), which is in agreement with the same finding in the studies of the broad-line regions. The lack of evolution for the gas metallicity of the narrow-line regions implies that the major epoch of star formation in the host galaxies of these active galactic nuclei is at z > 4.Comment: 16 pages, 12 figures, submitted to Astronomy and Astrophysic

An Integrated Market for Electricity and Natural Gas Systems with Stochastic Power Producers

In energy systems with high shares of weather-driven renewable power sources, gas-fired power plants can serve as a back-up technology to ensure security of supply and provide short-term flexibility. Therefore, a tighter coordination between electricity and natural gas networks is foreseen. In this work, we examine different levels of coordination in terms of system integration and time coupling of trading floors. We propose an integrated operational model for electricity and natural gas systems under uncertain power supply by applying two-stage stochastic programming. This formulation co-optimizes day-ahead and real-time dispatch of both energy systems and aims at minimizing the total expected cost. Additionally, two deterministic models, one of an integrated energy system and one that treats the two systems independently, are presented. We utilize a formulation that considers the linepack of the natural gas system, while it results in a tractable mixed-integer linear programming (MILP) model. Our analysis demonstrates the effectiveness of the proposed model in accommodating high shares of renewables and the importance of proper natural gas system modeling in short-term operations to reveal valuable flexibility of the natural gas system. Moreover, we identify the coordination parameters between the two markets and show their impact on the system's operation and dispatch